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  X-ray absorption spectroscopy of the nucleotide bases at the carbon, nitrogen, and oxygen K-edges

Zubavichus, Y., Shaporenko, A., Korolkov, V., Grunze, M., & Zharnikov, M. (2008). X-ray absorption spectroscopy of the nucleotide bases at the carbon, nitrogen, and oxygen K-edges. The Journal of Physical Chemistry B, 112(44), 13711-13716. doi:10.1021/jp802453u.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-9A5F-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-9A60-5
Genre: Journal Article

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JPhysChemB_112_2008_13711.pdf (Any fulltext), 498KB
 
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 Creators:
Zubavichus, Yan, Author
Shaporenko, Andrey, Author
Korolkov, Vladimir, Author
Grunze, Michael1, Author           
Zharnikov, Michael, Author
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: Near-edge X-ray absorption fine structure spectra of three pyrimidine (viz., cytosine, uracil, and thymine) and two purine (viz., adenine and guanine) nucleobases, which are the key constituents of DNA and RNA, were measured at the C, N, and O K-edges using the self-absorption-free partial electron yield mode. The nucleobase samples were prepared as highly pure native polycrystalline powder films. The spectra are analyzed in terms of the electronic structure of the nucleobases. Subtle chemical effects related to the molecular structures of these heterocyclic compounds with extended pi-electron systems are considered and discussed.

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Language(s): eng - English
 Dates: 2008-03-202008-07-022008-10-092008-10-09
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jp802453u
URI: https://www.ncbi.nlm.nih.gov/pubmed/18842017
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Title: The Journal of Physical Chemistry B
  Other : J. Phys. Chem. B
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 112 (44) Sequence Number: - Start / End Page: 13711 - 13716 Identifier: ISSN: 1520-6106
CoNE: https://pure.mpg.de/cone/journals/resource/1000000000293370_1