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  Structural determination and population transfer of 4-nitroanisole by broadband microwave spectroscopy and tailored microwave pulses

Graneek, J. B., Pérez, C., & Schnell, M. (2017). Structural determination and population transfer of 4-nitroanisole by broadband microwave spectroscopy and tailored microwave pulses. The Journal of Chemical Physics, 147(15): 154306. doi:10.1063/1.4991902.

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 Urheber:
Graneek, J. B.1, 2, Autor           
Pérez, C.1, 2, Autor           
Schnell, M.1, 2, 3, Autor           
Affiliations:
1Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
2Deutsches Elektronen-Synchrotron DESY, ou_persistent22              
3Christian-Albrechts-Universität zu Kiel, ou_persistent22              

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 Zusammenfassung: The rotational spectrum of 4-nitroanisole was recorded via chirped-pulse Fourier transform microwave spectroscopy in the frequency range of 2-8 GHz. The spectra of the parent molecule and all of its 13C-, 15N-, and 18O-monosubstituted species in their natural abundance were assigned, and the molecular structure was determined using Kraitchman’s equations as well as a least-square fitting approach. 4-nitroanisole has a large dipole moment of 6.15 D along the inertial a-axis and a smaller dipole moment of 0.78 D along the b-axis. The large dipole moment component makes this molecule a potential candidate for deceleration experiments using static electric fields or electromagnetic radiation. Using tailored microwave pulses, we investigate the possibility of transferring population between the rotational states of 4-nitroanisole. Such a technique could be applied to selectively increase the population for specific rotational states of interest, which are then accessible for further, more advanced experiments, such as deceleration.

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Sprache(n): eng - English
 Datum: 2017-06-232017-09-282017-10-172017-10-21
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1063/1.4991902
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Projektname : Crist ́ obal P ́ erez is grateful for support via a postdoctoral research fellowship from the Alexander von Humboldt Foun- dation. We acknowledge the use of the GWDG computer cluster.
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Quelle 1

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Titel: The Journal of Chemical Physics
  Andere : J. Chem. Phys.
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Woodbury, N.Y. : American Institute of Physics
Seiten: - Band / Heft: 147 (15) Artikelnummer: 154306 Start- / Endseite: - Identifikator: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226