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  Periodicity in the BrO/SO2 molar ratios in the volcanic gas plume of Cotopaxi and its correlation with the Earth tides during the eruption in 2015

Dinger, F., Bobrowski, N., Warnach, S., Bredemeyer, S., Hidalgo, S., Arellano, S., et al. (2018). Periodicity in the BrO/SO2 molar ratios in the volcanic gas plume of Cotopaxi and its correlation with the Earth tides during the eruption in 2015. SOLID EARTH, 9(2), 247-266. doi:10.5194/se-9-247-2018.

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Dinger, Florian1, Author           
Bobrowski, Nicole1, Author           
Warnach, Simon2, Author
Bredemeyer, Stefan2, Author
Hidalgo, Silvana2, Author
Arellano, Santiago2, Author
Galle, Bo2, Author
Platt, Ulrich2, Author
Wagner, Thomas1, Author           
Affiliations:
1Satellite Remote Sensing, Max Planck Institute for Chemistry, Max Planck Society, ou_1826293              
2external, ou_persistent22              

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 Abstract: We evaluated NOVAC (Network for Observation of Volcanic and Atmospheric Change) gas emission data from the 2015 eruption of the Cotopaxi volcano (Ecuador) for BrO∕SO2 molar ratios. The BrO∕SO2 molar ratios were very small prior to the phreatomagmatic explosions in August 2015, significantly higher after the explosions, and continuously increasing until the end of the unrest period in December 2015. These observations together with similar findings in previous studies at other volcanoes (Mt. Etna, Nevado del Ruiz, Tungurahua) suggest a possible link between a drop in BrO∕SO2 and a future explosion. In addition, the observed relatively high BrO∕SO2 molar ratios after December 2015 imply that bromine degassed predominately after sulfur from the magmatic melt. Furthermore, statistical analysis of the data revealed a conspicuous periodic pattern with a periodicity of about 2 weeks in a 3-month time series. While the time series is too short to rule out a chance recurrence of transient geological or meteorological events as a possible origin for the periodic signal, we nevertheless took this observation as a motivation to examine the influence of natural forcings with periodicities of around 2 weeks on volcanic gas emissions. One strong aspirant with such a periodicity are the Earth tides, which are thus central in this study. We present the BrO∕SO2 data, analyse the reliability of the periodic signal, discuss a possible meteorological or eruption-induced origin of this signal, and compare the signal with the theoretical ground surface displacement pattern caused by the Earth tides. Our central result is the observation of a significant correlation between the BrO∕SO2 molar ratios with the north–south and vertical components of the calculated tide-induced surface displacement with correlation coefficients of 47 and 36 %, respectively. From all other investigated parameters, only the correlation between the BrO∕SO2 molar ratios and the relative humidity in the local atmosphere resulted in a comparable correlation coefficient of about 33 %.

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 Dates: 2018
 Publication Status: Issued
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 Identifiers: ISI: 000426914900001
DOI: 10.5194/se-9-247-2018
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Title: SOLID EARTH
Source Genre: Journal
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Pages: - Volume / Issue: 9 (2) Sequence Number: - Start / End Page: 247 - 266 Identifier: ISSN: 1869-9510