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  Solvation of oligo(ethylene glycol)-terminated self-assembled monolayers studied by vibrational sum frequency spectroscopy

Zolk, M., Eisert, F., Pipper, J., Herrwerth, S., Eck, W., Buck, M., et al. (2000). Solvation of oligo(ethylene glycol)-terminated self-assembled monolayers studied by vibrational sum frequency spectroscopy. Langmuir, 16(14), 5849-5852. doi:10.1021/la0003239.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-BC02-9 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-BC03-8
Genre: Journal Article

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Langmuir_16_2000_5849.pdf (Any fulltext), 59KB
 
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 Creators:
Zolk, M., Author
Eisert, F., Author
Pipper, J., Author
Herrwerth, S., Author
Eck, W., Author
Buck, M., Author
Grunze, M.1, Author           
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: Self-assembled monolayers of methyl(1-mercaptoundec-11-yl)tri(ethylene glycol) (CH3O(C2H4O)3C11H22SH, EG3-OMe) adsorbed on gold were investigated by IR−vis sum frequency generation in the range of the C−H stretching vibrations. Comparison of the monolayers in ambient atmosphere, in contact with water, and in contact with carbon tetrachloride revealed that the film structure is strongly disturbed by the interaction of the liquid with the monolayer. The ordered structure found in air undergoes an amorphization upon exposure to the solvents. The experiments demonstrate that in situ analysis of the film structure is mandatory.

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Language(s): eng - English
 Dates: 2000-04-262000-03-032000-06-082000
 Publication Status: Issued
 Pages: 4
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 Rev. Type: Peer
 Identifiers: DOI: 10.1021/la0003239
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Title: Langmuir
Source Genre: Journal
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Publ. Info: Columbus, OH : American Chemical Society
Pages: - Volume / Issue: 16 (14) Sequence Number: - Start / End Page: 5849 - 5852 Identifier: ISSN: 0743-7463
CoNE: https://pure.mpg.de/cone/journals/resource/954925541194