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  Local structure of amorphous ice as revealed by O K-edge EXAFS

Zubavichus, Y., Yang, Y., Zharnikov, M., Fuchs, O., Schmidt, T., Heske, C., et al. (2004). Local structure of amorphous ice as revealed by O K-edge EXAFS. ChemPhysChem, 5(4), 509-514. doi:10.1002/cphc.200300842.

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 Creators:
Zubavichus, Yan, Author
Yang, Yongjie, Author
Zharnikov, Michael, Author
Fuchs, Oliver, Author
Schmidt, Thomas, Author
Heske, Clemens, Author
Umbach, Eberhard, Author
Tzvetkov, George, Author
Netzer, Falko P., Author
Grunze, Michael1, Author           
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1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: The oxygen K-edge extended X-ray absorption fine structure (EXAFS) spectrum of an ice film prepared by deposition of water vapor on a substrate at 100 K was measured in the surface-sensitive Auger yield mode. Five distinct peaks are revealed in the Fourier transform spectrum of the EXAFS data. The peaks are attributed to O-H bonds (with overlapping contributions from intramolecular covalent and intermolecular hydrogen bonds) as well as to intermolecular O...O scattering paths in the distance range of 1-7 A. The pattern of the longer O...O distances resembles that of a high-pressure crystalline modification of ice (ice II).

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Language(s): eng - English
 Dates: 2003-05-142004-01-142004-04-19
 Publication Status: Issued
 Pages: 6
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 Rev. Type: Peer
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Title: ChemPhysChem
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 5 (4) Sequence Number: - Start / End Page: 509 - 514 Identifier: ISSN: 1439-4235
CoNE: https://pure.mpg.de/cone/journals/resource/954925409790