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  Kaolin: A Natural Low-Cost Material as Catalyst for Isomerization of Glucose to Fructose

Pienkoß, F., Ochoa-Hernandez, C., Theyssen, N., & Leitner, W. (2018). Kaolin: A Natural Low-Cost Material as Catalyst for Isomerization of Glucose to Fructose. ACS Sustainable Chemistry & Engineering, 6(7), 8782-8789. doi:10.1021/acssuschemeng.8b01151.

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 Creators:
Pienkoß, Fabian1, 2, Author              
Ochoa-Hernandez, Cristina3, Author              
Theyssen, Nils1, Author              
Leitner, Walter2, 4, Author
Affiliations:
1Service Department Theyssen (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445632              
2Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, 52074 Aachen, Germany, ou_persistent22              
3Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
4Max-Planck-Institut für Chemische Energiekonversion, Stiftstr. 34-36, 45470 Mülheim, Germany, ou_persistent22              

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Free keywords: Biomass conversion; Catalysis; Clay materials; Fructose; Glucose isomerization
 Abstract: Kaolin was identified as an effective catalyst for isomerization of glucose to fructose in methanol. The methyl-fructoside is obtained as main product through in situ etherification at the anomeric carbon atom, reflecting the bifunctionality of the layered alumosilicate. Using this exceptionally cheap and abundant natural clay (0.16 $/kg), methyl-fructoside is produced with up to 52% yield.

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Language(s): eng - English
 Dates: 2018-03-132017-06-072018-07-02
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acssuschemeng.8b01151
 Degree: -

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Title: ACS Sustainable Chemistry & Engineering
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 6 (7) Sequence Number: - Start / End Page: 8782 - 8789 Identifier: ISSN: 2168-0485
CoNE: https://pure.mpg.de/cone/journals/resource/2168-0485