English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Where's water? The many binding sites of hydantoin

Gruet, S., Pérez, C., Steber, A. L., & Schnell, M. (2018). Where's water? The many binding sites of hydantoin. Physical Chemistry Chemical Physics, 20(8), 5545-5552. doi:10.1039/c7cp06518c.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/21.11116/0000-0001-F5FE-D Version Permalink: http://hdl.handle.net/21.11116/0000-0001-F5FF-C
Genre: Journal Article

Files

show Files
hide Files
:
c7cp06518c.pdf (Publisher version), 3MB
Name:
c7cp06518c.pdf
Description:
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2018
Copyright Info:
© the Author(s)

Locators

show
hide
Locator:
https://dx.doi.org/10.1039/c7cp06518c (Publisher version)
Description:
-

Creators

show
hide
 Creators:
Gruet, Sébastien1, 2, 3, Author              
Pérez, C.1, 2, 3, Author              
Steber, A. L.1, 2, 3, Author              
Schnell, M.1, 2, 3, Author              
Affiliations:
1Structure and Dynamics of Cold and Controlled Molecules, Independent Research Groups, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_1938292              
2Deutsches Elektronensychrotron, ou_persistent22              
3Institut für Physikalische Chemie, Christian-Albrechts-Universität zu Kiel, ou_persistent22              

Content

show
hide
Free keywords: -
 Abstract: Prebiotic hydantoin and its complexes with one and two water molecules are investigated using high-resolution broadband rotational spectroscopy in the 2–8 GHz frequency range. The hyperfine structure due to the nuclear quadrupole coupling of the two 14N atoms is analysed for the monomer and the complexes. This characteristic hyperfine structure will support a definitive assignment from low frequency radioastronomy data. Experiments with H218O provide accurate experimental information on the preferred binding sites of water, which are compared with quantum-chemically calculated coordinates. In the 2-water complexes, the water molecules bind to hydantoin as a dimer instead of individually, indicating the strong water–water interactions. This information provides first insight on how hydantoin interacts with water on the molecular level.

Details

show
hide
Language(s): eng - English
 Dates: 2017-09-222017-11-222018-02-28
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/c7cp06518c
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 20 (8) Sequence Number: - Start / End Page: 5545 - 5552 Identifier: ISSN: 1463-9076
CoNE: /journals/resource/954925272413_1