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  Carbocatalysis : analyzing the sources of organic transformations

Antonietti, M., Navalón, S., Dhakshinamoorthy, A., Álvaro, M., & García, H. (2018). Carbocatalysis: analyzing the sources of organic transformations. In L. Dai (Ed.), Carbon-Based Metal-Free Catalysts: Design and Applications, I (pp. 285-311). Weinheim: Wiley-VCH. doi:10.1002/9783527811458.vol1-ch10.

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 Creators:
Antonietti, Markus1, Author              
Navalón, Sergio, Author
Dhakshinamoorthy, Amarajothi, Author
Álvaro, Mercedes, Author
García, Hermenegildo, Author
Affiliations:
1Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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Free keywords: carbocatalysis, density functional theory, hydrothermally treated graphene oxide, metal-free carbocatalysts, nucleophilicity
 Abstract: Carbon nanostructures were found to be powerful metal-free catalysts. This chapter reviews some families of such reactions and elaborates on the diverse defects and chemical functionalities onto the graphene layers that are thought to catalyze such reactions, such as oxygenated functional groups, carbon vacancies and holes, edge effects, and the presence of dopant elements. In addition to discrete active sites, the catalytic activity arisen from the collective properties of conjugated nanocarbons and the electron transfer to substrates and adsorbed catalysts are also commented. This chapter is concluded with some of our perspectives on future developments in the field.

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 Dates: 2018-09-032018-10-08
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/9783527811458.vol1-ch10
 Degree: -

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Title: Carbon-Based Metal-Free Catalysts: Design and Applications, I
Source Genre: Book
 Creator(s):
Dai, Liming, Editor
Affiliations:
-
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 285 - 311 Identifier: ISBN: 9783527811458 (online)
ISBN: 9783527343416
DOI: 10.1002/9783527811458