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  Structure and Thermal Stability of Stilbenedithiol SAMs on Au(111)

Völkner, J., Bashir, A., Parak, W. J., & Witte, G. (2018). Structure and Thermal Stability of Stilbenedithiol SAMs on Au(111). Physica Status Solidi A, 215(15): 1700859. doi:10.1002/pssa.201700859.

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 Creators:
Völkner, Johannes1, Author           
Bashir, Asif2, Author           
Parak, Wolfgang J.1, Author           
Witte, Gregor3, Author           
Affiliations:
1Fachbereich Physik, Philipps-Universität Marburg, Renthof 7, Marburg, 35032, Germany, persistent22              
2Corrosion, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society, ou_2074315              
3Molekulare Festkörperphysik, Philipps-Universität Marburg, D-35032 Marburg, Germany, ou_persistent22              

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Free keywords: Monolayers; Sulfur compounds; Thermodynamic stability; X ray absorption, Bivalent linking layers; Characterization techniques; High thermal stability; Near-edge x-ray absorption; Photoelectrochemical sensors; Preparation parameters; Self-assembling monolayers; Stilbenedithiol, Film preparation
 Abstract: Self-assembling monolayers (SAMs) of dithiols play an important role as bivalent linker layer in applications such as photoelectrochemical sensors. However, their formation processes and film structure are not fully understood yet. Herein, a SAM of aromatic trans-stilbenedithiol (StDT) on Au(111) surfaces is investigated. Using complementary characterization techniques the dependence of the film quality on preparation parameters, such as used solvent, temperature and ambient conditions during and subsequent to preparation is investigated. Furthermore, a remarkably high thermal stability is found which is ascribed to disulfide bridging between the endgroups of the individual molecules. © 2018 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim

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Language(s): eng - English
 Dates: 2018-08-08
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/pssa.201700859
BibTex Citekey: Völkner2018
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Title: Physica Status Solidi A
  Other : Physica Status Solidi A: Applications and Materials Science
  Abbreviation : Phys. Stat. Sol. (a)
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 215 (15) Sequence Number: 1700859 Start / End Page: - Identifier: ISSN: 1862-6300
CoNE: https://pure.mpg.de/cone/journals/resource/1862630