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  Brønsted Acid Mediated Direct α-Hydroxylation of Cyclic α-Branched Ketones

Shevchenko, G. A., Dehn, S., & List, B. (2018). Brønsted Acid Mediated Direct α-Hydroxylation of Cyclic α-Branched Ketones. Synlett, 29(17), 2298-2300. doi:10.1055/s-0037-1610292.

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Genre: Journal Article

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 Creators:
Shevchenko, Grigory A.1, Author              
Dehn, Stefanie1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: α-branched ketones; α-hydroxylation; aminoxylation; α-functionalization of ketones; enolization; Brønsted acid mediated
 Abstract: We report a Brønsted acid mediated direct α-hydroxylation of cyclic α-branched ketones via a tandem aminoxylation/N–O bond-cleavage process. Nitrosobenzene is used as the oxidant and subsequently promotes the liberation of the free alcohol. The desired products could be isolated in moderate to good yields at a maximum tested scale of 10 mmol. Derivatizations of the obtained products are presented.

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Language(s): eng - English
 Dates: 2018-08-212018-09-022018-09-262018-10-23
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0037-1610292
 Degree: -

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Title: Synlett
  Other : Synlett
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 29 (17) Sequence Number: - Start / End Page: 2298 - 2300 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856