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  Magnetic Study of a Layered Lanthanide Hydroxide family: Ln8(OH)20Cl4·nH2O (Ln = Tb, Ho, Er)

Coutinho, J. T., Pereira, C. C. L., Marçalo, J., Baldovi, J., Almeida, M., Monteiro, B., et al. (2018). Magnetic Study of a Layered Lanthanide Hydroxide family: Ln8(OH)20Cl4·nH2O (Ln = Tb, Ho, Er). Dalton Transactions, 47(45), 16211-16217. doi:10.1039/C8DT03672A.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0002-5FDB-E Version Permalink: http://hdl.handle.net/21.11116/0000-0003-225C-0
Genre: Journal Article

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https://dx.doi.org/10.1039/C8DT03672A (Publisher version)
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 Creators:
Coutinho, J. T.1, 2, Author
Pereira, C. C. L.3, Author
Marçalo, J.1, 4, Author
Baldovi, J.5, Author              
Almeida, M.1, Author
Monteiro, B.1, 4, Author
Pereira, L. C. J.1, Author
Affiliations:
1Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, ou_persistent22              
2Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, ou_persistent22              
3LAQV-REQUIMTE, Dep. de Química, Universidade Nova de Lisboa, ou_persistent22              
4Centro de Química Estrutural (CQE), Instituto Superior Técnico, Universidade de Lisboa, Campus Tecnológico e Nuclear, ou_persistent22              
5Theory Group, Theory Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_2266715              

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 Abstract: Three layered lanthanide hydroxides (LLHs), with the general formula Ln8(OH)20Cl4·nH2O (Ln = Tb (1), Ho (2), Er (3)), were prepared and magnetically characterized. These compounds were further diluted within a yttrium diamagnetic matrix, LYH:xLn, LYH:0.044Tb (1’), LYH:0.045Ho (2’), and LYH:0.065Er (3’), being the study complemented with theoretical calculations in order to understand the electronic configuration and the contributions to the slow relaxation behavior. In the pure compounds dominant 3D ferromagnetic interactions are observed, with a small magnetization hysteresis at 1.8 K for 1, while the magnetically diluted solid solutions display slow relaxation of the magnetization at low temperatures.

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Language(s): eng - English
 Dates: 2018-09-112018-10-222018-10-222018-12-07
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C8DT03672A
 Degree: -

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Project name : We thank the Fundação para a Ciência e a Tecnologia (FCT) for financial support through the UID/Multi/04349/2013 project (C2TN), UID/QUI/50006/2013 (LAQV-REQUIMTE), grants to J. T. C. (SFRH/BD/84628/2012) and C. C. L. P. (SFRH/BPD/ 108959/2015) and contract to BM (contract n° IST-ID/077/2018). We thank the EU for project “ SunStorage- Harvesting and storage of solar energy ” (POCI-01-0145-FEDER-016387), funded by European Regional Development Fund (ERDF) and co-financed by the ERDF under the PT2020 Partnership Agreement (POCI-01- 0145-FEDER – 007265), through COMPETE 2020 – Operational Programme for Competitiveness and Internationalization (OPCI), (COST Action CA15128 MOLSPIN and ERC-2014-CoG-647301 DECRESIM) and the Spanish MINECO (Unit of excellence “ Maria de Maeztu ” MDM-2015-0538). J. J. B. thanks the EU for a Marie Curie Fellowship (H2020-MSCA-IF-2016-751047).
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Source 1

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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: 7 Volume / Issue: 47 (45) Sequence Number: - Start / End Page: 16211 - 16217 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323