English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  A Highly Reduced Ni–Li–Olefin Complex for Catalytic Kumada–Corriu Cross-Couplings

Nattmann, L., Lutz, S., Ortsack, P., Goddard, R., & Cornella, J. (2018). A Highly Reduced Ni–Li–Olefin Complex for Catalytic Kumada–Corriu Cross-Couplings. Journal of the American Chemical Society, 140(42), 13628-13633. doi:10.1021/jacs.8b09849.

Item is

Basic

show hide
Genre: Journal Article

Files

show Files
hide Files
:
ja8b09849_si_004-1.pdf (Supplementary material), 4MB
Name:
ja8b09849_si_004-1.pdf
Description:
Supporting Information
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
ja8b09849_si_003.cif (Supplementary material), 14KB
Name:
ja8b09849_si_003.cif
Description:
Crystallographic data for complex 1
Visibility:
Public
MIME-Type / Checksum:
text/plain / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
ja8b09849_si_002.cif (Supplementary material), 10KB
Name:
ja8b09849_si_002.cif
Description:
Crystallographic data for complex 22
Visibility:
Public
MIME-Type / Checksum:
text/plain / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Nattmann, Lukas1, Author              
Lutz, Sigrid1, Author              
Ortsack, Pascal1, Author              
Goddard, Richard2, Author              
Cornella, Josep1, Author              
Affiliations:
1Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2466693              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

Content

show
hide
Free keywords: -
 Abstract: The catalytic activity of a highly reduced Ni catalyst in the context of a Kumada–Corriu cross-coupling has been studied. This nickel complex is characterized by its high electron density, stabilized by simple olefin ligands in combination with two Li ions. Landmark reactivity has been found with this precatalyst which operates at cryogenic temperatures, thus allowing the presence of sensitive functionalities. Structural elucidation of oxidative addition intermediates and their reactivity suggest highly reduced species being operative in the C–C bond forming event.

Details

show
hide
Language(s): eng - English
 Dates: 2018-09-112018-10-102018-10-24
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.8b09849
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of the American Chemical Society
  Other : J. Am. Chem. Soc.
  Abbreviation : JACS
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 140 (42) Sequence Number: - Start / End Page: 13628 - 13633 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870