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  From a Molecular Single-Source Precursor to a Selective High- Performance RhMnOx Catalyst for the Conversion of Syngas to Ethanol

Preikschas, P., Bauer, J., Huang, X., Yao, S., d’Alnoncourt, R. N., Kraehnert, R., et al. (2019). From a Molecular Single-Source Precursor to a Selective High- Performance RhMnOx Catalyst for the Conversion of Syngas to Ethanol. ChemCatChem, 11(2), 885-892. doi:10.1002/cctc.201801978.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0002-AD14-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-7769-0
Genre: Journal Article

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 Creators:
Preikschas, Phil1, Author
Bauer, Julia1, Author
Huang, Xing2, Author           
Yao, Shenglai3, Author
d’Alnoncourt, Raoul Naumann1, Author
Kraehnert, Ralph1, Author
Trunschke, Annette2, Author           
Rosowski, Frank1, 4, Author
Driess, Matthias1, 3, Author
Affiliations:
1BasCat – UniCat BASF JointLab, Technische Universität Berlin, Hardenbergstraße 36, Sekr. EW-K01, 10623 Berlin (Germany), ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
3Metalorganic Chemistry and Inorganic Materials, Department of Chemistry, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, 10623 Berlin (Germany), ou_persistent22              
4BASF SE, Process Research and Chemical Engineering Heterogeneous Catalysis, Carl -Bosch- Strasse 38, 67056 Ludwigshafen (Germany), ou_persistent22              

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 Abstract: The first carbonyl RhMn cluster Na2[Rh3Mn3(CO)18] 2 has been synthesized and structurally characterized, resulting from the salt metathesis reaction of RhCl3 with Na[Mn(CO)5] 1 in 49% isolated yield. The dianionic Rh3Mn3 cluster core of 2 can serve as a molecular single‐source precursor (SSP) for the low temperature preparation of selective high‐performance RhMn catalysts for the conversion of syngas to ethanol (StE). Impregnation of 2 on silica (davisil) led to three different silica‐supported RhMnOx catalysts with dispersed Rh nanoparticles tightly surrounded by a MnOx matrix. With ethanol selectivities of up to 24.1%, the Rh3Mn3 cluster precursor‐derived catalysts show the highest reported selectivity and performance in the conversion of StE for silica‐supported RhMnOx catalysts.

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Language(s): eng - English
 Dates: 2018-12-042018-12-062019-01-23
 Publication Status: Published online
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/cctc.201801978
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Title: ChemCatChem
  Other : ChemCatChem
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: 8 Volume / Issue: 11 (2) Sequence Number: - Start / End Page: 885 - 892 Identifier: ISSN: 1867-3880
CoNE: https://pure.mpg.de/cone/journals/resource/1867-3880