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  In(CH3COO)3: The first example of group 13 elements triacetate with an infinite chain crystal structure

Churakov, A. V., Vinokurov, A. A., Znamekov, K. O., Mordvinova, N. E., Gippius, A. A., Zhurenko, S. V., et al. (2019). In(CH3COO)3: The first example of group 13 elements triacetate with an infinite chain crystal structure. Polyhedron, 160, 42-45. doi:10.1016/j.poly.2018.12.024.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0002-BBC5-D Version Permalink: http://hdl.handle.net/21.11116/0000-0002-BDA3-1
Genre: Journal Article

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 Creators:
Churakov, Andrei V.1, Author
Vinokurov, Alexander A.1, Author
Znamekov, Konstantin O.1, Author
Mordvinova, Natalia E.1, Author
Gippius, Andrei A.1, Author
Zhurenko, Sergei V.1, Author
Baenitz, Michael2, Author              
Istomin, Sergey Ya.1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Michael Baenitz, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863471              

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Free keywords: Indium acetate, X-ray diffraction, Crystal structure, NMR spectroscopy, NQR spectroscopy
 Abstract: Single crystals of In(CH3COO)3 have been prepared by dissolution of basic indium carbonate In(OH)CO3 in a mixture of anhydrous acetic acid and acetic anhydride. The crystal structure of In(CH3COO)3 has been solved and refined for the first time using single crystal X-ray diffraction data. It has a unique crystal structure buildup of 1D chains of InO7 pentagonal bipyramids running along [0 1 0]. The compound has been characterized by 115In NMR and NQR spectroscopy. Rather high values of quadrupole constant (CQ = 182(1) MHz) and asymmetry parameter (η = 0.38) extracted from numerical simulation of experimental 115In NMR and NQR spectra agree with large distortion and asymmetric coordination of In3+ in the crystal structure of In(CH3COO)3.

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Language(s): eng - English
 Dates: 2019-01-032019-01-03
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1016/j.poly.2018.12.024
 Degree: -

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Title: Polyhedron
  Other : Polyhedron
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 160 Sequence Number: - Start / End Page: 42 - 45 Identifier: ISSN: 0277-5387
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228_2