English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  In(CH3COO)3: The first example of group 13 elements triacetate with an infinite chain crystal structure

Churakov, A. V., Vinokurov, A. A., Znamekov, K. O., Mordvinova, N. E., Gippius, A. A., Zhurenko, S. V., et al. (2019). In(CH3COO)3: The first example of group 13 elements triacetate with an infinite chain crystal structure. Polyhedron, 160, 42-45. doi:10.1016/j.poly.2018.12.024.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0002-BBC5-D Version Permalink: https://hdl.handle.net/21.11116/0000-0002-BDA3-1
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Churakov, Andrei V.1, Author
Vinokurov, Alexander A.1, Author
Znamekov, Konstantin O.1, Author
Mordvinova, Natalia E.1, Author
Gippius, Andrei A.1, Author
Zhurenko, Sergei V.1, Author
Baenitz, Michael2, Author           
Istomin, Sergey Ya.1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Michael Baenitz, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863471              

Content

show
hide
Free keywords: Indium acetate, X-ray diffraction, Crystal structure, NMR spectroscopy, NQR spectroscopy
 Abstract: Single crystals of In(CH3COO)3 have been prepared by dissolution of basic indium carbonate In(OH)CO3 in a mixture of anhydrous acetic acid and acetic anhydride. The crystal structure of In(CH3COO)3 has been solved and refined for the first time using single crystal X-ray diffraction data. It has a unique crystal structure buildup of 1D chains of InO7 pentagonal bipyramids running along [0 1 0]. The compound has been characterized by 115In NMR and NQR spectroscopy. Rather high values of quadrupole constant (CQ = 182(1) MHz) and asymmetry parameter (η = 0.38) extracted from numerical simulation of experimental 115In NMR and NQR spectra agree with large distortion and asymmetric coordination of In3+ in the crystal structure of In(CH3COO)3.

Details

show
hide
Language(s): eng - English
 Dates: 2019-01-032019-01-03
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1016/j.poly.2018.12.024
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Polyhedron
  Other : Polyhedron
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 160 Sequence Number: - Start / End Page: 42 - 45 Identifier: ISSN: 0277-5387
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228_2