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  Synthesis and structural relationship of complex tantalum phosphates in the flux system K2O-P2O5-Ta2O5-MoO3

Babaryk, A., Odynets, I., Baumer, V., Slobodyanik, N., Khainakov, S., & Hoffmann, S. (2012). Synthesis and structural relationship of complex tantalum phosphates in the flux system K2O-P2O5-Ta2O5-MoO3. In IEEE International Conference on Oxide Materials for Electronic Engineering (OMEE) (pp. 99-100). Retrieved from https://www.scopus.com/inward/record.uri?eid=2-s2.0-84881632942&doi=10.1109%2fOMEE.2012.6464783&partnerID=40&md5=a61844c629f86d5434e88010ca5d81d0.

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Babaryk, A.A.1, Author
Odynets, I.V.1, Author
Baumer, V.N.1, Author
Slobodyanik, N.S.1, Author
Khainakov, S.1, Author
Hoffmann, S.2, Author              
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1External Organizations, ou_persistent22              
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              

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 Abstract: Single crystals of K2Ta4O11 (I), K(TaO2)2PO4 (II) and K3Ta 5O11(PO4)2 (III) were synthesized by flux-aided method in the pseudo-quaternary system K2O-P 2O5-Ta2O5-MoO3. Tight interrelation of their crystal structures has been found via X-ray diffraction study. Experimental solid-state band gap measurements revealed its semiconductor nature corroborated with DFT calculations. Local structure of PO4 groups in (II) and (III) compounds was probed with 31P MAS NMR spectroscopy. © 2012 IEEE.

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Language(s): eng - English
 Dates: 2012-09-032012-09-03
 Publication Status: Published in print
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Title: IEEE International Conference on Oxide Materials for Electronic Engineering (OMEE)
Source Genre: Proceedings
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Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 99 - 100 Identifier: -