English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  High Lithium Transference Number Electrolytes Containing Tetratriflylpropene’s Lithium Salt

Popovic, J., Höfler, D., Melchior, J. P., Münchinger, A., List, B., & Maier, J. (2018). High Lithium Transference Number Electrolytes Containing Tetratriflylpropene’s Lithium Salt. The Journal of Physical Chemistry Letters, 9(17), 5116-5120. doi:10.1021/acs.jpclett.8b01846.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0002-CD11-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0004-626E-3
Genre: Journal Article

Files

show Files
hide Files
:
Popovic, Höfler, Melchior, Münchinger, List, Maier 2018.pdf (Postprint), 921KB
View   Save
File Permalink:
https://hdl.handle.net/21.11116/0000-0004-626F-2
Name:
Popovic, Höfler, Melchior, Münchinger, List, Maier 2018.pdf
Description:
Postprint
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Popovic, Jelena1, Author           
Höfler, Denis2, Author           
Melchior, J. P.1, Author
Münchinger, Andreas1, Author
List, Benjamin2, Author           
Maier, Joachim1, Author           
Affiliations:
1Max Planck Institute for Solid State Research, Stuttgart, Germany, ou_persistent13              
2Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

Content

show
hide
Free keywords: -
 Abstract: Electrolytes with a high lithium transference number linked with high ionic conductivity are urgently needed for high power battery operation. In this work, we present newly synthesized lithium tetra(trifluoromethanesulfonyl)propene as a salt-in-glyme-based “salt-in-solvent” electrolyte. We employ impedance spectroscopy in symmetric Li/electrolyte/Li cells and pulsed field gradient nuclear magnetic resonance spectroscopy to investigate the lithium conduction mechanism. We find predominant lithium conductivity with very high lithium transference numbers (∼70% from the polarization experiments) and three times higher ionic conductivity compared to well-known lithium triflate in diglyme electrolyte. This is a consequence of the reduced mobilities of large anions linked with improved ionic dissociation.

Details

show
hide
Language(s): eng - English
 Dates: 2018-06-132018-08-022018-08-022018-09-06
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.jpclett.8b01846
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: The Journal of Physical Chemistry Letters
  Abbreviation : J. Phys. Chem. Lett.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 9 (17) Sequence Number: - Start / End Page: 5116 - 5120 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/1948-7185