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  Total Synthesis of (−)-Sinulariadiolide. A Transannular Approach

Meng, Z., & Fürstner, A. (2019). Total Synthesis of (−)-Sinulariadiolide. A Transannular Approach. Journal of the American Chemical Society, 141(2), 805-809. doi:10.1021/jacs.8b12185.

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ja8b12185_si_001-1_supporting information.pdf (Supplementary material), 7MB
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ja8b12185_si_001-1_supporting information.pdf
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 Creators:
Meng, Zhanchao1, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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 Abstract: The constrained tricyclic skeleton of the nor-cembranoid sinulariadiolide (1) with a nine-membered nexus was obtained by a cascade of transannular Michael reaction, carbonate elimination, butenolide formation, and spontaneous oxa-Michael addition of MeOH. The required macrocyclic precursor was prepared by ring-closing alkyne metathesis followed by trans-hydrostannation/carbonylation.

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Language(s): eng - English
 Dates: 2018-11-212018-12-202019-01-16
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.8b12185
 Degree: -

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Title: Journal of the American Chemical Society
  Other : J. Am. Chem. Soc.
  Abbreviation : JACS
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 141 (2) Sequence Number: - Start / End Page: 805 - 809 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870