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  Indirectly transmitted charge‐transfer interactions: multilayered [2.2] paracyclophane quinhydrones

Staab, H. A., Zapf, U., & Gurke, A. (1977). Indirectly transmitted charge‐transfer interactions: multilayered [2.2] paracyclophane quinhydrones. Angewandte Chemie, 16(11), 801-803. doi:10.1002/anie.197708011.

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AngewChemIntEd_16_1977_801.pdf (Any fulltext), 364KB
 
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Staab, Heinz A.1, Author           
Zapf, Udo2, Author           
Gurke, Anneliese2, Author           
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              
2Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              

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 Abstract: [2.2] Paracyclophane quinhydrones with intercalated benzene rings have now been synthesized for the first time in the form of their methyl ethers (1) and (2). Their broad CT band must be due to an intramolecular CT transition; the charge is transmitted in “vertical conjugation” through the π‐electron system of the benzene. Orientation dependence of the CT absorption as observed in simple donor‐acceptor 2.2 paracyclophanes is almost completely absent.
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Language(s): eng - English
 Dates: 1977-09-262003-12-221977-11
 Publication Status: Issued
 Pages: 3
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 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.197708011
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Title: Angewandte Chemie
  Abbreviation : Angew. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 16 (11) Sequence Number: - Start / End Page: 801 - 803 Identifier: ISSN: 0044-8249
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058_1