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  Determination of the 14N quadrupole tensor of phenazine in its lowest excited triplet state by ODNQR

Dinse, K., & Winscom, C. J. (1978). Determination of the 14N quadrupole tensor of phenazine in its lowest excited triplet state by ODNQR. The Journal of Physical Chemistry, 68, 1337-1343. doi:10.1063/1.435951.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0003-2AED-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0003-2AEE-3
Genre: Journal Article

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JChemPhys_68_1978_1337.pdf (Any fulltext), 2MB
 
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 Creators:
Dinse, Klaus−Peter1, Author           
Winscom , C. J., Author
Affiliations:
1Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              

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 Abstract: The first complete determination of the 14N nuclear quadrupole tensor in the photoexcited triplet state of an organic molecule was made feasible by an alternative to ODENDOR. Instead of using a simultaneous desaturation method (cw‐ODENDOR), a procedure involving sequential population transfer between specific electron–nuclear spin levels was adopted. This new method is demonstrated for phenazine‐d8 in a Shpolskii matrix and yields ‖e2qQ/h‖= (4.36±0.02) MHz; η=+0.21±0.03.

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Language(s): eng - English
 Dates: 1977-06-101978-02-15
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.435951
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Title: The Journal of Physical Chemistry
  Abbreviation : J. Phys. Chem.
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 68 Sequence Number: - Start / End Page: 1337 - 1343 Identifier: ISSN: 1932-7447
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766_3