English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Sr4N[CN2][C2N]: The First Carbodiimide Acetonitriletriide

Jach, F., Höhn, P., Prots, Y., & Ruck, M. (2019). Sr4N[CN2][C2N]: The First Carbodiimide Acetonitriletriide. European Journal of Inorganic Chemistry, (9), 1207-1211. doi:10.1002/ejic.201801242.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/21.11116/0000-0003-36FF-2 Version Permalink: http://hdl.handle.net/21.11116/0000-0003-3704-B
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Jach, Franziska1, Author              
Höhn, Peter2, Author              
Prots, Yurii3, Author              
Ruck, Michael4, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              
3Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
4Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

Content

show
hide
Free keywords: -
 Abstract: The acetonitriletriide anion C2N3-, the fully deprotonated form of acetonitrile, is stabilized in a pure alkaline earth metal environment in Sr4N[CN2][C2N]. The heterogeneous reaction of graphite and elemental nitrogen (from decomposed NaN3) with Sr2N at 1020 K yields for the first time a phase that contains the two triatomic anions acetonitriletriide C2N3- and carbodiimide CN22- side by side. Further synthetic routes were likewise successfully tested, including a sodium free approach (Sr2N + C) and the use of NaCN as carbon and nitrogen source. The monoclinic crystal structure is derived from powder and single-crystal X-ray diffraction data (P2(1)/c, a = 397.74(1) pm, b = 1411.72(3) pm, c = 692.57(1) pm, beta = 103.57(1)degrees, Z = 2). The existence of both anions in Sr4N[CN2][C2N] is further confirmed by IR and Raman spectroscopy. With its novel 1-D chain structure of edge-sharing NSr6 octahedra, the material also enriches the structural variety of ternary alkaline earth metal nitrides.

Details

show
hide
Language(s): eng - English
 Dates: 2019-02-162019-02-16
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000460581100003
DOI: 10.1002/ejic.201801242
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: European Journal of Inorganic Chemistry
  Abbreviation : Eur. J. Inorg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: (9) Sequence Number: - Start / End Page: 1207 - 1211 Identifier: ISSN: 1434-1948
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810_1