English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  2D correlation spectroscopy in homonuclear dipolar-coupled solids

Schuff, N., & Haeberlen, U. (1983). 2D correlation spectroscopy in homonuclear dipolar-coupled solids. Journal of Magnetic Resonance, 52(2), 267-281. doi:10.1016/0022-2364(83)90194-4.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0003-5FE0-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0003-5FE1-5
Genre: Journal Article

Files

show Files
hide Files
:
JMagnReson_52_1983_267.pdf (Any fulltext), 947KB
 
File Permalink:
-
Name:
JMagnReson_52_1983_267.pdf
Description:
-
OA-Status:
Visibility:
Restricted (Max Planck Institute for Medical Research, MHMF; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Creators

show
hide
 Creators:
Schuff, Norbert1, Author           
Haeberlen, Ulrich2, Author           
Affiliations:
1Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              
2Research Group Prof. Dr. Haeberlen, Max Planck Institute for Medical Research, Max Planck Society, ou_1497739              

Content

show
hide
Free keywords: -
 Abstract: A novel 2D proton solid-state NMR experiment is described in which the spins evolve freely during the evolution period, while they are decoupled from each other by a multiple-pulse sequence in the detection period. The resulting 2D spectrum allows the correlation of chemical shifts with dipolar interactions. It is useful for assigning proton chemical shift tensors and for recording simplified wide-line spectra whose meaning is discussed in terms of a “gedanken” experiment. The method is applied to a single crystal of malonic acid (MA). The long-standing problem of assigning the previously measured proton chemical shift tensors in MA to the proton sites is solved. For the first time line splittings are resolved which result from dipolar interactions of the carboxylic protons in MA. They are discussed in terms of the geometry of the hydrogen bonds formed by these protons.

Details

show
hide
Language(s): eng - English
 Dates: 1982-11-042004-06-301983-04
 Publication Status: Issued
 Pages: 15
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-2364(83)90194-4
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of Magnetic Resonance
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: San Diego [etc.] : Academic Press
Pages: - Volume / Issue: 52 (2) Sequence Number: - Start / End Page: 267 - 281 Identifier: ISSN: 0022-2364
CoNE: https://pure.mpg.de/cone/journals/resource/954922651175_1