English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Crystal Growth and Structure Determination of Pigment Orange 82

Kaiser, M., Wosylus, A., Gerke, B., Pöttgen, R., Prokeš, K., Ruck, M., et al. (2019). Crystal Growth and Structure Determination of Pigment Orange 82. Zeitschrift für anorganische und allgemeine Chemie, 645(6-7), 564-569. doi:10.1002/zaac.201800499.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/21.11116/0000-0003-63CB-9 Version Permalink: http://hdl.handle.net/21.11116/0000-0003-63CD-7
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Kaiser, Martin1, Author
Wosylus, Aron1, Author
Gerke, Birgit1, Author
Pöttgen, Rainer1, Author
Prokeš, Karel1, Author
Ruck, Michael2, Author              
Doert, Thomas1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

Content

show
hide
Free keywords: -
 Abstract: The crystal structure of the important industrial orange pigment PO82, major part of the BASF Colors & EffectsA (R) product SicopalA (R) Orange K/L 2430, was solved from combined X-ray single crystal, X-ray and neutron powder diffraction, Sn-119 Mossbauer spectroscopy, transmission electron microscopy, electron diffraction, and chemical analyses. The structure contains Keggin type clusters composed of four [M3O13] trimers consisting each of three MO6 octahedra that share edges and one common oxygen atom connecting the trimers to the central ZnO4 tetrahedron. The octahedrally coordinated metal atom position is mixed occupied by Ti4+, Sn4+, and Zn2+. Adjacent Keggin clusters share vertices and are further interconnected to four ZnO4 tetrahedra. This framework of interconnected MO6 octahedra and ZnO4 tetrahedra contains channels along [110], in which the Sn2+ cations are located.

Details

show
hide
Language(s): eng - English
 Dates: 2019-02-052019-02-05
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000462768300002
DOI: 10.1002/zaac.201800499
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : J. Inorg. Gen Chem.
  Other : Journal of Inorganic and General Chemistry
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 645 (6-7) Sequence Number: - Start / End Page: 564 - 569 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895