English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  Probing the effect of surface strain on CO binding to Pd thin films.

Harding, D. J., Bongers, M. D., Wagner, S., Hahn, H., Neugebohren, J., Kitsopoulos, T. N., et al. (2019). Probing the effect of surface strain on CO binding to Pd thin films. The Journal of Physical Chemistry C, 123(19), 12255-12260. doi:10.1021/acs.jpcc.9b01435.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0003-969B-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0003-9BDE-5
Genre: Journal Article

Files

show Files
hide Files
:
3054551.pdf (Publisher version), 2MB
 
File Permalink:
-
Name:
3054551.pdf
Description:
-
OA-Status:
Visibility:
Restricted ( Max Planck Society (every institute); )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
3054551_Suppl.pdf (Supplementary material), 2MB
View   Save
File Permalink:
https://hdl.handle.net/21.11116/0000-0003-9BE0-1
Name:
3054551_Suppl.pdf
Description:
-
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Harding, D. J., Author
Bongers, M. D., Author
Wagner, S., Author
Hahn, H.1, Author           
Neugebohren, J.1, Author           
Kitsopoulos, T. N.2, Author           
Wodtke, A. M.2, Author           
Pundt, A., Author
Affiliations:
1Department of Dynamics at Surfaces, MPI for Biophysical Chemistry, Max Planck Society, ou_578600              
2Department of Dynamics at Surfaces, MPI for biophysical chemistry, Max Planck Society, ou_578600              

Content

show
hide
Free keywords: -
 Abstract: We report measurements to investigate the effects of mechanical strain on the binding energy of carbon monoxide (CO) on the (111) surface of a 16 nm thin film of palladium (Pd) grown on rutile titanium dioxide (r-TiO2). The lattice mismatch between Pd and the r-TiO2 leads to a tensile mechanical in-plane stress in the Pd layer of approximately 0.38 GPa. We observe an increase of (40 ± 10) kJ mol–1 in the CO binding energy for the 16 nm sample compared to a bulk Pd(111) crystal, which is in qualitative agreement with expectations based on the d-band model.

Details

show
hide
Language(s): eng - English
 Dates: 2019-04-112019
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.jpcc.9b01435
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: The Journal of Physical Chemistry C
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 123 (19) Sequence Number: - Start / End Page: 12255 - 12260 Identifier: -