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  Transition metal-mediated metathesis between P–C and M–C bonds: Beyond a side reaction

Lee, Y. H., & Morandi, B. (2019). Transition metal-mediated metathesis between P–C and M–C bonds: Beyond a side reaction. Coordination Chemistry Reviews, 386(5), 96-118. doi:10.1016/j.ccr.2018.12.001.

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 Creators:
Lee, Yong Ho1, 2, Author              
Morandi, Bill1, 2, Author              
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland, ou_persistent22              

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 Abstract: Phosphine ligands often play an important role in controlling reactivity and selectivity in transition metal catalyzed reactions. However, one common drawback of the phosphine ligands is the undesired occurrence of an interchange between P bound aryl and M bound aryl or alkyl groups in the catalytic cycle. This results in the formation of undesirable coupling products as well as changes in catalyst structure through the replacement of the phosphine ligand. This review discusses approaches to understand this metathesis reaction between P–C and M–C and its productive application in catalytic reactions.

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Language(s): eng - English
 Dates: 2018-08-012018-12-082019-02-142019-05-01
 Publication Status: Published in print
 Pages: 23
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.ccr.2018.12.001
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Title: Coordination Chemistry Reviews
  Other : Coord. Chem. Rev.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 386 (5) Sequence Number: - Start / End Page: 96 - 118 Identifier: ISSN: 0010-8545
CoNE: https://pure.mpg.de/cone/journals/resource/954925393339