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  Interaction of Gold with Oxide Nanoparticles: Size or Electronic Effect?

Bondarchuk, O., Shaikhutdinov, S. K., & Freund, H.-J. (2019). Interaction of Gold with Oxide Nanoparticles: Size or Electronic Effect? The Journal of Physical Chemistry C, 123(19), 12376-12381. doi:10.1021/acs.jpcc.9b02592.

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 Creators:
Bondarchuk, Oleksandr1, Author           
Shaikhutdinov, Shamil K.1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              

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 Abstract: We have studied the interaction of gold with highly dispersed silica particles and flat silica films using scanning tunneling microscopy, X-ray photoelectron spectroscopy, and infrared spectroscopy. The results revealed the definitive role of the oxide morphology on the electronic structure, thermal stability, and CO adsorption capabilities of gold species formed. Comparison with our previous study of gold supported on ceria nanoparticles and films suggests that it is the nanoparticulate morphology of the oxide support rather than its reducibility that promotes the formation and stabilization of partially charged Auδ+ species.

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Language(s): eng - English
 Dates: 2019-04-292019-03-192019-04-292019-05-16
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.jpcc.9b02592
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Title: The Journal of Physical Chemistry C
  Abbreviation : J. Phys. Chem. C
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: 6 Volume / Issue: 123 (19) Sequence Number: - Start / End Page: 12376 - 12381 Identifier: ISSN: 1932-7447
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766