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  Palladium‐Catalyzed Intermolecular Aryliodination of Internal Alkynes

Lee, Y. H., & Morandi, B. (2019). Palladium‐Catalyzed Intermolecular Aryliodination of Internal Alkynes. Angewandte Chemie International Edition, 58(19), 6444-6448. doi:10.1002/anie.201812396.

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Genre: Journal Article

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 Creators:
Lee, Yong Ho1, 2, Author              
Morandi, Bill1, 2, Author              
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland, ou_persistent22              

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Free keywords: alkenyl iodides; aryliodination; carbohalogenation; homogeneous catalysis; palladium
 Abstract: A completely atom economical palladium‐catalyzed addition reaction has been developed to stereoselectively access functionalized tetrasubstituted alkenyl iodides. The palladium catalyst, which bears an electron‐poor bidentate ligand rarely employed in catalysis, is essential to promote the high yielding and chemoselective intermolecular reaction between equimolar amounts of an alkyne and an aryl iodide. This new carbohalogenation reaction is an attractive alternative to traditional synthetic methods, which rely on multistep synthetic sequences and protecting‐group manipulations.

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Language(s): eng - English
 Dates: 2018-10-292019-02-272019-05-06
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201812396
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie, International Edition
  Other : Angew. Chem. Int. Ed.
Source Genre: Journal
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Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 58 (19) Sequence Number: - Start / End Page: 6444 - 6448 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851