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  IDPi Catalysis

Schreyer, L., Properzi, R., & List, B. (2019). IDPi Catalysis. Angewandte Chemie International Edition, 58(37), 12761-12777. doi:10.1002/anie.201900932.

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Genre: Journal Article

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 Creators:
Schreyer, Lucas1, Author              
Properzi, Roberta1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: ACDC; Brønsted acids; enantioselective catalysis; Lewis acids; organocatalysis; silylium ions
 Abstract: High acidity and structural confinement are pivotal elements in asymmetric acid catalysis. The recently introduced imidodiphosphorimidate (IDPi) Brønsted acids have met with remarkable success in combining those features, acting as powerful Brønsted acid catalysts and “silylium” Lewis acid precatalysts in numerous thus far inaccessible transformations. Substrates as challenging to activate as simple olefins were readily transformed, ketones were employed as acceptors in aldolizations allowing sub‐ppm level catalysis, whereas enolates of the smallest donor aldehyde, acetaldehyde, did not polymerize but selectively added a single time to a variety of acceptor aldehydes.

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Language(s): eng - English
 Dates: 2019-01-232019-03-062019-09-09
 Publication Status: Published in print
 Pages: 17
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201900932
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 58 (37) Sequence Number: - Start / End Page: 12761 - 12777 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851