English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  A nitrate-selective microelectrode based on a lipophilic derivative of iodocobalt(III)salen

Verschuren, P., van der Baan, J., Blaauw, R., de Beer, D., & van den Heuvel, J. (1999). A nitrate-selective microelectrode based on a lipophilic derivative of iodocobalt(III)salen. Fresenius' Journal of Analytical Chemistry, 364(6), 595-598. doi:10.1007/s002160051392.

Item is

Files

show Files
hide Files
:
De_Beer_1999.pdf (Publisher version), 58KB
 
File Permalink:
-
Name:
De_Beer_1999.pdf
Description:
-
OA-Status:
Visibility:
Restricted ( Max Planck Society (every institute); )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Verschuren, P.G., Author
van der Baan, J.L., Author
Blaauw, R., Author
de Beer, Dirk1, Author           
van den Heuvel, J.C., Author
Affiliations:
1Permanent Research Group Microsensor, Max Planck Institute for Marine Microbiology, Max Planck Society, ou_2481711              

Content

show
hide
Free keywords: -
 Abstract: The synthesis of iodo {2,2'-[1,2-octadecanediylbis(nitrilomethylidyne)]diphenolato} cobalt is described. Liquid membrane microelectrodes based on this carrier exhibit Nernstian behaviour with a selectivity sequence according to the Hofmeister series: I- > NO3- = > NO2- > Cl- > HCO3- > AcO-. The selectivity coefficient of nitrate over nitrite and chloride amounts to -1.6 and -2.7, respectively. The detection limit for nitrate in water amounts to 10(-5.2) mol/L. A nitrate profile measured in a nitrifying biofilm is presented as a practical application.

Details

show
hide
Language(s): eng - English
 Dates: 1999
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000081853800018
DOI: 10.1007/s002160051392
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Fresenius' Journal of Analytical Chemistry
  Abbreviation : Fresenius. J. Anal. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Berlin : Springer International
Pages: - Volume / Issue: 364 (6) Sequence Number: - Start / End Page: 595 - 598 Identifier: ISSN: 0937-0633
CoNE: https://pure.mpg.de/cone/journals/resource/954928484272