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  Hydroxyapatite nanowires rich in [Ca–O–P] sites for ethanol direct coupling showing high C6–12 alcohol yield

Wang, Q.-N., Zhou, B.-C., Weng, X.-F., Lv, S.-P., Schüth, F., & Lu, A.-H. (2019). Hydroxyapatite nanowires rich in [Ca–O–P] sites for ethanol direct coupling showing high C6–12 alcohol yield. Chemical Communications, 55(70), 10420-10423. doi:10.1039/C9CC05454E.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0004-91F7-1 Version Permalink: http://hdl.handle.net/21.11116/0000-0004-91F8-0
Genre: Journal Article

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 Creators:
Wang, Qing-Nan1, Author
Zhou, Bai-Chuan1, Author
Weng, Xue-Fei1, Author
Lv, Shao-Pei1, Author
Schüth, Ferdi2, Author              
Lu, An-Hui1, Author
Affiliations:
1State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China, ou_persistent22              
2Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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 Abstract: Herein, we have shown that the [Ca–O–P] sites exposed on hydroxyapatite are clearly responsible for C–C formation in ethanol direct-coupling, and their high density accelerates the C–C coupling rate and boosts C6–12 alcohol production. Notably, nanowire-like hydroxyapatite exhibited 30.4% selectivity to n-butanol and 63.9% selectivity to C6–12OH at a conversion of 45.7% at 325 °C, and thereby close to 30% yield of C6–12OH, which is greatly higher than that using the state-of-the-art catalysts (6%).

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Language(s): eng - English
 Dates: 2019-07-162019-08-052019-08-052019-09-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1039/C9CC05454E
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 55 (70) Sequence Number: - Start / End Page: 10420 - 10423 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413