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  Ternary Phase Diagram-Facilitated Rapid Screening of Double Perovskites As Electrocatalysts for the Oxygen Evolution Reaction

Sun, H., Hu, Z., Xu, X., He, J., Dai, J., Lin, H.-J., et al. (2019). Ternary Phase Diagram-Facilitated Rapid Screening of Double Perovskites As Electrocatalysts for the Oxygen Evolution Reaction. Chemistry of Materials, 31(15), 5919-5926. doi:10.1021/acs.chemmater.9b02261.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0004-922D-5 Version Permalink: http://hdl.handle.net/21.11116/0000-0004-9231-F
Genre: Journal Article

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 Creators:
Sun, Hainan1, Author
Hu, Zhiwei2, Author              
Xu, Xiaomin1, Author
He, Juan1, Author
Dai, Jie1, Author
Lin, Hong-Ji1, Author
Chan, Ting-Shan1, Author
Chen, Chien-Te1, Author
Tjeng, Liu Hao3, Author              
Zhou, Wei1, Author
Shao, Zongping1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863461              
3Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              

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 Abstract: The development of cost-effective, non-noble metal electrocatalysts for the oxygen evolution reaction (OER) is of paramount importance for sustainable technologies. Efficient screening strategies for electrocatalysts can greatly increase the commercialization speed of these advanced technologies. Here, ternary phase diagrams with large-scale tuning and designated-scale tuning strategies are applied for the first time to provide a new method for screening perovskite oxide-based electrocatalysts for OERs. Specifically, the family of double perovskites (Sr2Fe1.5-x-yCoxNiyMo0.5O6-delta, 0 <= x, y <= 1.5) was utilized to understand the role of transition metals in perovskite oxides. Ternary phase diagrams can facilitate a rapid screening process, provide a straightforward relationship between phase structures and catalytic activities, and help to confirm the effects of various combinations of transition metals on the OER activity. The Fe-Co system (Sr2Fe1.5-xCoxMo0.5O6-delta) improves the catalytic activities, as demonstrated by the reduced Tafel slope and enhanced stability, while the Fe-Ni system (Sr2Fe1.5-yNiyMo0.5O6-delta) improves the surface kinetic properties of the OER, as demonstrated by its reduced overpotential. Significantly, the Co, Ni, and Fe ternary phase systems can serve as the synergistic coactive sites (Sr2Fe1.5-x-yCoxNiyMo0.5O6-delta) to catalyze the OER, resulting in an improved overall OER performance. This systematic study not only demonstrates a new strategy to allow the rapid screening of double perovskite OER catalysts based on large-scale tuning and designated-scale tuning strategies but, more importantly, also provides an insightful understanding of the use of multitransition metal-based double perovskites for catalysis of the OER.

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Language(s): eng - English
 Dates: 2019-07-222019-07-22
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1021/acs.chemmater.9b02261
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Title: Chemistry of Materials
  Abbreviation : Chem. Mater.
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 31 (15) Sequence Number: - Start / End Page: 5919 - 5926 Identifier: ISSN: 0897-4756
CoNE: https://pure.mpg.de/cone/journals/resource/954925561571