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  Molybdenum Alkylidyne Complexes with Tripodal Silanolate Ligands: The Next Generation of Alkyne Metathesis Catalysts

Hillenbrand, J., Leutzsch, M., & Fürstner, A. (2019). Molybdenum Alkylidyne Complexes with Tripodal Silanolate Ligands: The Next Generation of Alkyne Metathesis Catalysts. Angewandte Chemie, International Edition, 58(44), 15690-15696. doi:10.1002/anie.201908571.

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ange201908571-s1-supporting_information_revised-v2.pdf (Supplementary material), 7MB
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ange201908571-s1-supporting_information_revised-v2.pdf
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 Creators:
Hillenbrand, Julius1, Author              
Leutzsch, Markus2, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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Free keywords: alkylidyne complexes; alkyne metathesis; molybdenum; podands; silanolate ligands
 Abstract: A new type of molybdenum alkylidyne catalyst for alkyne metathesis is described, which is distinguished by an unconventional podand topology. These structurally well‐defined complexes are easy to make on scale and proved to be tolerant toward numerous functional groups; even certain protic substituents were found to be compatible. The new catalysts were characterized by X‐ray crystallography and by spectroscopic means, including 95Mo NMR.

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Language(s): eng - English
 Dates: 2019-07-102019-08-262019-08-262019-10-28
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201908571
 Degree: -

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Title: Angewandte Chemie, International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 58 (44) Sequence Number: - Start / End Page: 15690 - 15696 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851