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  Optical detection of chlorine NQR of p-dichlorobenzene in a mixed single crystal in a magnetic field

Deimling, M., & Dinse, K. (1980). Optical detection of chlorine NQR of p-dichlorobenzene in a mixed single crystal in a magnetic field. Chemical Physics Letters, 69(3), 587-591. doi:10.1016/0009-2614(80)85134-7.

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ChemPhysLett_69_1980_587.pdf (Any fulltext), 360KB
 
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 Creators:
Deimling, Michael1, Author           
Dinse, Klaus−Peter1, Author           
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1Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              

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 Abstract: By a combined optical and microwave pumping cycle, chlorine NQR transitions could be observed for a dilute mixed single crystal of p-dichlorobenzene (p-DCB) in p-dibromobenzene (p-DBB). From the line splittings in the NQR spectrum of the singlet ground state of p-DCB for an orientation of the external magnetic field Bo parallel to one of the in-plane fine structure axes, a considerable deviation (Δθ = 12°, Δφ = 20°) of this axis from a direction expected for an undistorted triplet-state molecule can be calculated. In addition, a lower limit of the electric field-gradient asymmetry parameter (η > 0.06) for singlet state p-DCB in the p-DBB matrix at 1.2 K is established.

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Language(s): eng - English
 Dates: 1979-10-302001-11-271980-02-01
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0009-2614(80)85134-7
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Title: Chemical Physics Letters
  Other : Chem. Phys. Lett.
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 69 (3) Sequence Number: - Start / End Page: 587 - 591 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241