English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Computational Investigations into the Mechanisms of Trans-Selective Hydrogenation and Hydrometalation of Alkynes

Wolf, L. M., & Thiel, W. (2019). Computational Investigations into the Mechanisms of Trans-Selective Hydrogenation and Hydrometalation of Alkynes. In M. Zhou (Ed.), Catalysis by Metal Complexes & Nanomaterials - Fundamentals & Applications (pp. 57-69). Washington: American Chemical Society. doi:10.1021/bk-2019-1317.ch003.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Wolf, Lawrence M.1, 2, Author           
Thiel, Walter2, Author           
Affiliations:
1Department of Chemistry, University of Massachusetts Lowell, 1 University Avenue, Lowell, Massachusetts 01854, United States, ou_persistent22              
2Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              

Content

show
hide
Free keywords: -
 Abstract: An overview on the mechanisms of the trans-selective hydrogenation and hydrometalation of alkynes using a CpRuL catalyst is provided. Unlike the more common mode of hydrogenation, syn, this select ruthenium catalyst system uniquely favors the products resulting from anti-addition across the alkyne π-system. The primary focus is summarizing the results of computational studies on the mechanism of these reactions, including key experimental supporting evidence. This chapter addresses hydrogenation, hydrosilylation, hydrostannation, and hydroboration. An overview of the mechanisms for all of these processes is highlighted.

Details

show
hide
Language(s): eng - English
 Dates: 2019-07-122019-01-01
 Publication Status: Published in print
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/bk-2019-1317.ch003
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Catalysis by Metal Complexes & Nanomaterials - Fundamentals & Applications
Source Genre: Book
 Creator(s):
Zhou, Meng1, Editor
Affiliations:
1 Lawrence Technological University, Southfield, Michigan United States, ou_persistent22            
Publ. Info: Washington : American Chemical Society
Pages: - Volume / Issue: ACS Symposium Series, 1317 Sequence Number: - Start / End Page: 57 - 69 Identifier: ISBN: 9780841234376