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  One-pot photocalalytic reductive formylation of nitroarenes via multielectron transfer by carbon nitride in functional eutectic medium

Markushyna, Y., Völkel, A., Savateev, A., Antonietti, M., & Filonenko, S. (2019). One-pot photocalalytic reductive formylation of nitroarenes via multielectron transfer by carbon nitride in functional eutectic medium. Journal of Catalysis, 380, 186-194. doi:10.1016/j.jcat.2019.10.010.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-0FBB-9 Version Permalink: http://hdl.handle.net/21.11116/0000-0005-5302-B
Genre: Journal Article

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Markushyna, Yevheniia1, Author              
Völkel, Antje2, Author              
Savateev, Aleksandr1, Author              
Antonietti, Markus3, Author              
Filonenko, Svitlana4, Author              
Affiliations:
1Aleksandr Savateev, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2421702              
2Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863288              
3Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              
4Svitlana Filonenko, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3158261              

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Free keywords: Organic photoredox catalysis, Deep eutectic solvents, Carbon nitride, Photoreduction, -arylformamides
 Abstract: In the past years organic semiconductor photocatalysis has made the remarkable advances in developing efficient synthetic chemical routes to well refined structures. Until now, most efforts were focused on optimizing of the semiconductor photocatalyst, while solvents were largely ignored. Herein, we design a series of functional deep eutectic solvents (DES) with adjustable physicochemical properties – density, viscosity, glass transition temperature, and chemical activity towards reductive formylation of nitroarenes. The DES are prepared from abundant, sustainable resources, which makes them an affordable alternative to the ionic liquids, even on larger industrial scales. By combining the ammonium formate-based DES with carbon nitride photocatalyst, we enable the simultaneous six-electron reduction of nitro-compounds to the corresponding N-substituted formamides and benzimidazoles in one pot.

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Language(s): eng - English
 Dates: 2019-11-062019
 Publication Status: Published in print
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 Rev. Method: -
 Identifiers: DOI: 10.1016/j.jcat.2019.10.010
BibTex Citekey: MARKUSHYNA2019
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Title: Journal of Catalysis
  Abbreviation : J. Catal.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 380 Sequence Number: - Start / End Page: 186 - 194 Identifier: ISSN: 0021-9517