English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  The preparation of new metallic charge-transfer complexes: anthra [9.1-cd:10.5-c′,d′] bis [1.2] dithiol (TTA), -diselenol (TSA) and their polyiodides

Endres, H., Keller, H., Queckbörner, J., Veigel, J., & Schweitzer, D. (1982). The preparation of new metallic charge-transfer complexes: anthra [9.1-cd:10.5-c′,d′] bis [1.2] dithiol (TTA), -diselenol (TSA) and their polyiodides. Molecular Crystals and Liquid Crystals, 86, 111-122. doi:10.1080/00268948208073674.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0005-54CD-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-54CE-5
Genre: Journal Article

Files

show Files
hide Files
:
MolCrystLiqCryst_86_1982_111.pdf (Any fulltext), 516KB
 
File Permalink:
-
Name:
MolCrystLiqCryst_86_1982_111.pdf
Description:
-
OA-Status:
Visibility:
Restricted (Max Planck Institute for Medical Research, MHMF; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Creators

show
hide
 Creators:
Endres , H., Author
Keller, H.J., Author
Queckbörner, J., Author
Veigel, J., Author
Schweitzer, Dieter1, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              

Content

show
hide
Free keywords: -
 Abstract: The donors TTA and TSA were prepared starting from 1.5-dichloro-9.10-anthracenedione which was converted into 1.5.9.10-tetrachloroan-thracene (TCA) by two alternating chlorination and elimination steps. TCA was reacted under a dry argon atmosphere with suspensions of Na2S2 and Na2Se2 to yield TTA and TSA, respectively. Action of elemental iodine gives highly conductive polyiodides of both donors. Single crystals of TSA·I1.2 actually behave metallic between 220 and 300 K. The X-ray structure of TSA and TSA·I1.2 allows a comparison of intermolecular distances in the neutral and the partially oxidized, ionic stacks of the donor.

Details

show
hide
Language(s): eng - English
 Dates: 1982
 Publication Status: Issued
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1080/00268948208073674
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Molecular Crystals and Liquid Crystals
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Philadelphia, Pa. : Taylor and Francis, Inc.
Pages: - Volume / Issue: 86 Sequence Number: - Start / End Page: 111 - 122 Identifier: ISSN: 1542-1406
CoNE: https://pure.mpg.de/cone/journals/resource/954925597576