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  Crystal structures of the tetrachloridoaluminates(III) of rubidium(I), silver(I), and lead(II)

Knies, M., Lê Anh, M., Keßler, U., & Ruck, M. (2020). Crystal structures of the tetrachloridoaluminates(III) of rubidium(I), silver(I), and lead(II). Zeitschrift für Naturforschung, B: A Journal of Chemical Sciences, 75(1-2), 117-123. doi:10.1515/znb-2019-0162.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-5F2C-1 Version Permalink: http://hdl.handle.net/21.11116/0000-0005-A10C-8
Genre: Journal Article

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 Creators:
Knies, Maximilian1, Author
Lê Anh, Mai1, Author
Keßler, Ulrich1, Author
Ruck, Michael2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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Free keywords: crystal structure, ionic liquids, tetrachloridoaluminate
 Abstract: The reactions of the binary metal chlorides AgCl, RbCl and PbCl2 at T = 180°C in the ionic liquid [BMIm]Cl · 4AlCl3 (BMIm = 1-n-butyl-3-methylimidazolium) yielded air-sensitive, colorless, high-quality crystals of their tetrachloridoaluminate(III) salts. Thereby, the obstructions that hinder proper crystallization of these compounds from pristine AlCl3 melts were circumvented. X-ray diffraction on single-crystals revealed a monoclinic structure (space group P21/c) for Ag[AlCl4], which unexpectedly has a closer relation to Cu[AlCl4]2 than to Cu[AlCl4]. Rb[AlCl4] crystallizes in the baryte structure type (orthorhombic, Pnma), and Pb[AlCl4]2 is isotypic to α-Sr[GaCl4]2 (orthorhombic, Pbca). © 2019 Walter de Gruyter GmbH, Berlin/Boston 2019.

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Language(s): eng - English
 Dates: 2020-01-222020-01-22
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: DOI: 10.1515/znb-2019-0162
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Title: Zeitschrift für Naturforschung, B: A Journal of Chemical Sciences
  Abbreviation : Z. Naturforsch., B: J. Chem. Sci.
Source Genre: Journal
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Publ. Info: Berlin : Walter de Gruyter GmbH
Pages: - Volume / Issue: 75 (1-2) Sequence Number: - Start / End Page: 117 - 123 Identifier: ISSN: 0932-0776
CoNE: https://pure.mpg.de/cone/journals/resource/954927655916