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  Simple theoretical considerations of counterion effects on proton chemical shifts in charged annulenes

Vogler, H. (1985). Simple theoretical considerations of counterion effects on proton chemical shifts in charged annulenes. Journal of the Chemical Society, Perkin Transactions 1, 1985(12), 2033-2036. doi:10.1039/P29850002033.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0005-74BE-3 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-74BF-2
Genre: Journal Article

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JChemSocPerkinTrans2_1985_1985_2033.pdf (Any fulltext), 481KB
 
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 Creators:
Vogler, Helmut1, Author           
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: Ring-current contributions to 1H chemical shifts of charged annulenes with (4m+ 2) and (4m)π-electrons are investigated by means of simple molecular orbital theory. It is shown that electrostatic and covalent interaction between annulene and counterion reduce the paratropism of (4m)π-electron annulenes but do not affect the diatropism of (4m+ 2)π-electron annulenes.

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Language(s): eng - English
 Dates: 1984-11-281985
 Publication Status: Issued
 Pages: 4
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/P29850002033
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Title: Journal of the Chemical Society, Perkin Transactions 1
Source Genre: Journal
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Publ. Info: London : Royal Society of Chemistry
Pages: - Volume / Issue: 1985 (12) Sequence Number: - Start / End Page: 2033 - 2036 Identifier: ISSN: 0300-9580