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  Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3-xPdx(BTC)2]n

Zhang, W., Chen, Z., Al-Naji, M., Guo, P., Cwik, S., Halbherr, O., et al. (2016). Simultaneous introduction of various palladium active sites into MOF via one-pot synthesis: Pd@[Cu3-xPdx(BTC)2]n. Dalton Transactions, 45(38), 14883-14887. doi:10.1039/c6dt02893d.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-7537-A Version Permalink: http://hdl.handle.net/21.11116/0000-0005-7538-9
Genre: Journal Article

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 Creators:
Zhang, Wenhua, Author
Chen, Zhihao, Author
Al-Naji, Majd1, Author              
Guo, Penghu, Author
Cwik, Stefan, Author
Halbherr, Olesia, Author
Wang, Yuemin, Author
Muhler, Martin, Author
Wilde, Nicole, Author
Glaeser, Roger, Author
Fischer, Roland A., Author
Affiliations:
1External Organizations, ou_persistent22              

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Free keywords: metal-organic framework; pd nanoparticles; catalytic-activity; hydrogen storage; complexes; sorption; btc; nitrophenol; reusability; selectivity
 Abstract: Simultaneous incorporation of palladium within Pd-Pd and/or Pd-Cu paddlewheels as framework-nodes and Pd nanoparticle (NP) dispersion into MOF have been achieved for the first time via one-pot synthesis. In particular, the framework substitution of Cu2+ by Pd2+ as well as the pore loading with PdNPs have been confirmed and characterized by XPS. The obtained solids featuring such multiple Pd-sites show enhanced catalytic activity in the aqueous-phase hydrogenation of p-nitrophenol (PNP) with NaBH4 to p-aminophenol (PAP).

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Language(s): eng - English
 Dates: 2016
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: ISI: 000385198400003
DOI: 10.1039/c6dt02893d
 Degree: -

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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 45 (38) Sequence Number: - Start / End Page: 14883 - 14887 Identifier: ISSN: 1477-9226