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  Unravelling reaction products of styrene oxide adsorbed on Ag(111) using REMPI-assisted temperature-programmed desorption.

Westphal, G., Wallrabe, M., & Schäfer, T. (2020). Unravelling reaction products of styrene oxide adsorbed on Ag(111) using REMPI-assisted temperature-programmed desorption. The Journal of Physical Chemistry, 124(1), 799-804. doi:10.1021/acs.jpcc.9b10358.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-90B6-A Version Permalink: http://hdl.handle.net/21.11116/0000-0005-90B9-7
Genre: Journal Article

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Westphal, G.1, Author              
Wallrabe, M.1, Author              
Schäfer, T.1, Author              
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1Department of Dynamics at Surfaces, MPI for Biophysical Chemistry, Max Planck Society, ou_578600              

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 Abstract: Adsorption of styrene oxide on Ag(111) at 200 K leads to the formation of a stable oxametallacycle by ring-opening of the epoxide. At elevated temperatures, the oxametallacycle reacts and the products desorb from the surface. We employ resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (REMPI-ToF-MS) to identify reaction products after desorption. We assign phenylacetaldehyde as the only product that desorbs at temperatures around 485 K.

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Language(s): eng - English
 Dates: 2019-12-042020
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1021/acs.jpcc.9b10358
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Title: The Journal of Physical Chemistry
Source Genre: Journal
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Pages: - Volume / Issue: 124 (1) Sequence Number: - Start / End Page: 799 - 804 Identifier: -