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  In Situ Induction of Strain in Iron Phosphide (FeP2) Catalyst for Enhanced Hydroxide Adsorption and Water Oxidation

Li, G., Yang, Q., Rao, J., Fu, C., Liou, S.-C., Auffermann, G., et al. (2020). In Situ Induction of Strain in Iron Phosphide (FeP2) Catalyst for Enhanced Hydroxide Adsorption and Water Oxidation. Advanced Functional Materials, 1907791, pp. 1-8. doi:10.1002/adfm.201907791.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0005-9553-5 Version Permalink: http://hdl.handle.net/21.11116/0000-0005-F5B5-A
Genre: Journal Article

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2020
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 Creators:
Li, Guowei1, Author              
Yang, Qun1, Author              
Rao, Jiancun2, Author
Fu, Chenguang1, Author              
Liou, Sz-Chian2, Author
Auffermann, Gudrun3, Author              
Sun, Yan1, Author              
Felser, Claudia4, Author              
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2External Organizations, ou_persistent22              
3Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863432              
4Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              

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 Abstract: Carbon-based materials have been widely used in heterogeneous catalysis because of their advantages of high surface area, thermal stability, and chemical inertness. However, their role in the catalysis is not fully understood although most studies conclude that the coupling between the carbon support and catalyst could reduce the charge transfer resistance and improve the kinetics of catalytic reactions such as water splitting. In this study, a carbon-modified FeP2 electrocatalyst with a one-step strategy is synthesized. The tensile strain is introduced in situ in the ab crystal plane of the FeP2 catalyst. This leads to charge redistribution between H and O atoms in the OH bonds and enhances the adsorption of reaction intermediates. In the water oxidation process, this results in a decrease in the energy barrier for the rate-determining step, specifically, the chemical step of *OH adsorption preceded by one-electron transfer. Benefiting from the optimized adsorption energy, the strained catalysts exhibit excellent oxygen evolution reaction (OER) activity with a low overpotential in addition to their increased stability. This study provides a new strategy for the introducing of strains in functional materials and provides new insights into the influence of carbon modification on OER activity.

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Language(s): eng - English
 Dates: 2020-01-202020-01-20
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000508509400001
DOI: 10.1002/adfm.201907791
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Title: Advanced Functional Materials
  Other : Adv. Funct. Mater.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH
Pages: - Volume / Issue: - Sequence Number: 1907791 Start / End Page: 1 - 8 Identifier: ISSN: 1616-301X
CoNE: https://pure.mpg.de/cone/journals/resource/954925596563