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  Electronic structure of 4,5-bis(dimethylamino)fluorene. PE spectroscopic investigations

Gleiter, R., Schaefer, W., Staab, H. A., & Saupe, T. (1984). Electronic structure of 4,5-bis(dimethylamino)fluorene. PE spectroscopic investigations. Journal of Organic Chemistry, 49(23), 4463-4465. doi:10.1021/jo00197a026.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0005-AA6E-1 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-AA6F-0
Genre: Journal Article

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JOrgChem_49_1984_4463.pdf (Any fulltext), 322KB
 
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https://pubs.acs.org/doi/pdf/10.1021/jo00197a026 (Any fulltext)
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 Creators:
Gleiter, Rolf, Author
Schaefer, Wolfgang, Author
Staab, Heinz A.1, Author           
Saupe, Thomas2, Author           
Affiliations:
1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              
2Max Planck Institute for Medical Research, Max Planck Society, ou_1125545              

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 Abstract: The He(I) photoelectron spectrum of 4,5-bis(dimethylamino)fluorene (1) has been recorded and compared
with those of 4-(dimethylamino)- and 4-aminofluorene, 3 and 4, respectively. The assignment of the PE spectra
is based on ZDO calculations and on the correlation of the bands. It is shown that the split between the two
lone pairs of the dimethylamino groups in 1 amounts to 2.2 eV. MINDO/3 calculations on 1, 3, and 4 reproduce
the PE results of 3 and 4 reasonably well but fail to reproduce the split of the lone pairs in 1.

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Language(s): eng - English
 Dates: 1984-03-121984-11-01
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jo00197a026
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Title: Journal of Organic Chemistry
  Other : JOC
  Abbreviation : J. Org. Chem.
Source Genre: Journal
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Publ. Info: Washington, D.C., etc. : American Chemical Society [etc.]
Pages: - Volume / Issue: 49 (23) Sequence Number: - Start / End Page: 4463 - 4465 Identifier: ISSN: 0022-3263
CoNE: https://pure.mpg.de/cone/journals/resource/954925416967