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  Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity

Budde, S., Goerdeler, F., Floß, J., Kreitmeier, P., Hicks, E. F., Moscovitz, O., et al. (2020). Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity. Organic Chemistry Frontiers, 7(14), 1789-1795. doi:10.1039/D0QO00168F.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0006-3E73-4 Version Permalink: http://hdl.handle.net/21.11116/0000-0006-C681-8
Genre: Journal Article

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 Creators:
Budde, Simon, Author
Goerdeler, Felix1, Author              
Floß, Johannes, Author
Kreitmeier, Peter, Author
Hicks, Elliot Frederick, Author
Moscovitz, Oren1, Author              
Seeberger, Peter H.2, Author              
Davies, Huw M. L., Author
Reiser, Oliver, Author
Affiliations:
1Oren Moscovitz, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3176803              
2Peter H. Seeberger - Vaccine Development, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863308              

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 Abstract: A visible light mediated ring expansion of readily available carbo- and heterocyclic anellated cyclopropanes by molecular oxygen at ambient pressure has been developed. Tolerating a variety of functional groups, the reaction yields fused 1,2-dioxolanes, which were tested for antimalarial activity given their close analogy to the active principle of approved drugs such as artemisinin.

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Language(s): eng - English
 Dates: 2020-04-092020
 Publication Status: Published in print
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 Identifiers: DOI: 10.1039/D0QO00168F
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Title: Organic Chemistry Frontiers
  Abbreviation : Org. Chem. Front.
Source Genre: Journal
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Publ. Info: London : Royal Society of Chemistry
Pages: - Volume / Issue: 7 (14) Sequence Number: - Start / End Page: 1789 - 1795 Identifier: ISSN: 2052-4129