ausblenden:
Schlagwörter:
NITROGEN-DIOXIDE; TROPOSPHERIC NO2; COLUMN RETRIEVAL; AIR-QUALITY;
OZONE; FORMALDEHYDE; SCIAMACHY; ALGORITHM; MISSION; PRECURSORMeteorology & Atmospheric Sciences;
Zusammenfassung:
Tropospheric NO2 and stratospheric NO2 vertical column densities are important TROPOspheric Monitoring Instrument (TROPOMI) data products. In order to validate the TROPOMI NO2 products, KNMI Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) instruments have measured NO2 on ship cruises over the Atlantic and the Pacific oceans. The MAX-DOAS instruments have participated in five cruises on board RV Sonne (in 2017 and 2019) and RV Maria S. Merian (in 2018). The MAX-DOAS measurements were acquired over 7 months and spanned about 90 degrees in latitude and 300 degrees in longitude. During the cruises aerosol measurements from Microtops sun photometers were also taken. The MAX-DOAS measured stratospheric NO2 columns between 1.5 x 10(15) and 3.5 x 10(15) molec cm(-2) and tropospheric NO2 up to 0.6 x 10(15) molec cm(-2). The MAX-DOAS stratospheric NO2 vertical column densities have been compared with TROPOMI stratospheric NO2 vertical column densities and the stratospheric NO2 vertical column densities simulated by the global chemistry Transport Model, version 5, Massively Parallel model (TM5-MP). Good correlation is found between the MAX-DOAS and TROPOMI and TM5 stratospheric NO2 vertical column densities, with a correlation coefficient of 0.93 or larger. The TROPOMI and TM5 stratospheric NO2 vertical column densities are about 0.4 x 10(15) molec cm(-2) (19 %) higher than the MAX-DOAS measurements. The TROPOMI tropospheric NO2 also has good agreement with the MAX-DOAS measurements. The tropospheric NO2 vertical column density is as low as 0.5 x 10(15) molec cm(-2) over remote oceans.
