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  Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications

Sharma, M. K., Blomeyer, S., Neumann, B., Stammler, H.-G., Hinz, A., van Gastel, M., et al. (2020). Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications. Chemical Communications, 56(24), 3575-3578. doi:10.1039/D0CC00624F.

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 Creators:
Sharma, Mahendra K.1, Author
Blomeyer, Sebastian1, Author
Neumann, Beate1, Author
Stammler, Hans-Georg1, Author
Hinz, Alexander2, Author
van Gastel, Maurice3, Author              
Ghadwal, Rajendra S.1, Author
Affiliations:
1Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstr. 25, Bielefeld, Germany , ou_persistent22              
2Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany , ou_persistent22              
3Research Group van Gastel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541713              

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 Abstract: 2-Arsa-1,3-butadienes (L)As(cAACR) (L = PhC=C{(NDipp)CH}2, Dipp = 2,6-iPr2C6H3; cAACR = C{(NDipp)CMe2CH2C(R)}, R = Me22a, R = cyclohexyl (Cy) 2b) and the corresponding radical cations [(L)As(cAACR)]GaCl4 (R = Me23a, Cy 3b) and dications [(L)As(cAACR)](GaCl4)2 (R = Me 4a, Cy 4b) featuring a C=C–As=C π-conjugated framework are reported.

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Language(s): eng - English
 Dates: 2020-01-222020-02-192020-02-192020-03-25
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/D0CC00624F
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 56 (24) Sequence Number: - Start / End Page: 3575 - 3578 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413