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  Synthesis of a new ruthenate Ba26Ru12O57

Lee, J.-E., Burkhardt, U., & Komarek, A. C. (2020). Synthesis of a new ruthenate Ba26Ru12O57. Crystals, 10: 355, pp. 1-12. doi:10.3390/cryst10050355.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0006-76E3-5 Version Permalink: http://hdl.handle.net/21.11116/0000-0006-76E5-3
Genre: Journal Article

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 Creators:
Lee, Jeong-Eun1, Author              
Burkhardt, Ulrich2, Author              
Komarek, Alexander Christoph3, Author              
Affiliations:
1Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863446              

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Free keywords: Dimer, Floating zone technique, High oxidation state, Kagome, Ruthenate, Singe cyrstal growth
 Abstract: Single crystals of Ba26Ru12O57 were grown by the floating zone method. The crystal structure is formed by an alternating stacking of pseudo-hexagonal Ru single layers and double layers. The Ru ions within the double layers are dimerized (Ru2O9) whereas the Ru ions within the single layers arrange in a distorted Kagome lattice of trigonal bipyramidally coordinated RuO5 polyhedra. Additionally, this Kagome lattice is "decorated" with RuO6 octahedra that are situated in the central free spaces within this Kagome lattice. According to the composition, the oxidation state of most of the Ru ions should be formally close to 5+. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

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Language(s): eng - English
 Dates: 2020-04-302020-04-30
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.3390/cryst10050355
 Degree: -

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Title: Crystals
Source Genre: Journal
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Publ. Info: Basel, Switzerland : MDPI AG
Pages: - Volume / Issue: 10 Sequence Number: 355 Start / End Page: 1 - 12 Identifier: ISSN: 2073-4352
CoNE: https://pure.mpg.de/cone/journals/resource/2073-4352