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  Benzo[c ]benzo[3,4]cinnolino[1,2‐a ]cinnolin, ein chirales Hydrazin‐Derivat

Fischer, H., Krieger, C., & Neugebauer, F. A. (1986). Benzo[c ]benzo[3,4]cinnolino[1,2‐a ]cinnolin, ein chirales Hydrazin‐Derivat. Angewandte Chemie, 98(4), 341-342. doi:10.1002/ange.19860980411.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0006-90AD-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0006-90AE-3
Genre: Journal Article

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AngewChem_98_1986_341.pdf (Any fulltext), 221KB
 
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https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.19860980411 (Any fulltext)
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 Creators:
Fischer, Hans1, Author           
Krieger, Claus1, Author           
Neugebauer, Franz A.1, Author           
Affiliations:
1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: Die spontane Kristallisation der Enantiomere wurde bei der Titelverbindung 1 (Raumgruppe P 21) beobachtet. Die Röntgen‐Strukturanalyse zeigt an den Stickstoffatomen eine pyramidale Anordnung der Substituenten. Die hohe Racemisierungsbarriere von 27.1 kcal mol−1 beruht überwiegend auf dem gauche ‐Effekt der vicinalen freien Elektronenpaare.

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Language(s): deu - German
 Dates: 1985-12-302006-01-271986-04
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ange.19860980411
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Title: Angewandte Chemie
  Abbreviation : Angew. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 98 (4) Sequence Number: - Start / End Page: 341 - 342 Identifier: ISSN: 0044-8249
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058_1