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  5,6,8,9-Tetraaza[3.3] paracylophane, transannular effect on the n → π transition

Neugebauer, F. A., & Fischer, H. (1986). 5,6,8,9-Tetraaza[3.3] paracylophane, transannular effect on the n → π transition. Tetrahedron Letters, 27(44), 5367-5370. doi:10.1016/S0040-4039(00)85212-0.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0006-9388-A Version Permalink: http://hdl.handle.net/21.11116/0000-0006-9389-9
Genre: Journal Article

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TetrahedronLett_27_1986_5367.pdf (Any fulltext), 196KB
 
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 Creators:
Neugebauer, Franz A.1, Author              
Fischer, Hans1, Author              
Affiliations:
1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: 5,6,8,9-Tetraaza[3.3]paracyclophane () and the corresponding 14,17-dimethoxy derivative were prepared. and exist as chair and boat conformers, the boat form being energetically favoured. Transannular interaction in and leads to a hypsochromic shift of the first n → π* absorption. The [3.3]paracyclophanes and were prepared; transannular interaction leads to a hypsochromic shift of the first n→π* band.

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Language(s): eng - English
 Dates: 1986-08-062001-04-021986
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4039(00)85212-0
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Title: Tetrahedron Letters
  Other : Tetrahedron Lett.
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 27 (44) Sequence Number: - Start / End Page: 5367 - 5370 Identifier: ISSN: 0040-4039
CoNE: https://pure.mpg.de/cone/journals/resource/954925448772