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  Electronic spectra and triplet state properties of superphane

Schweitzer, D., Hausser, K. H., Vogler, H., Staab, H. A., & Boekelheide, V. (1986). Electronic spectra and triplet state properties of superphane. Chemical Physics, 110(1), 93-101. doi:10.1016/0301-0104(86)85147-3.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0006-952B-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0006-952C-1
Genre: Journal Article

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ChemPhys_110_1986_93.pdf (Any fulltext), 869KB
 
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 Creators:
Schweitzer, Dieter1, Author           
Hausser, Karl H.1, Author           
Vogler, Helmut2, Author           
Staab, Heinz A.2, Author           
Boekelheide , V., Author
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1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: The emission and the zero-field splitting parameters D and E of the superphane 1 and the [25](1,2,3,4,5)-cyclophane 2 are investigated. The large number of six and five methylene bridges, respectively, leads to a more rigid molecular frame and to a smaller transanular distance as compared to other [2.2]cyclophanes. The experimental results exhibit characteristics features which are due to these unusual properties; they are discussed and compared with semi-empirical Π-electron calculations.

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Language(s): eng - English
 Dates: 1986-06-232001-11-161986-12-01
 Publication Status: Issued
 Pages: 9
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0301-0104(86)85147-3
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Title: Chemical Physics
  Other : Chem. Phys.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier B.V.
Pages: - Volume / Issue: 110 (1) Sequence Number: - Start / End Page: 93 - 101 Identifier: ISSN: 0301-0104
CoNE: https://pure.mpg.de/cone/journals/resource/954925509371