Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

 
 
DownloadE-Mail
  Y4Be33Pt16 - a non-centrosymmetric cage superconductor with multi-centre bonding in the framework

Amon, A., Svanidze, E., Prots, Y., Nicklas, M., Burkhardt, U., Ormeci, A., et al. (2020). Y4Be33Pt16 - a non-centrosymmetric cage superconductor with multi-centre bonding in the framework. Dalton Transactions, 49(27), 9362-9368. doi:10.1039/d0dt01374a.

Item is

Basisdaten

einblenden: ausblenden:
Genre: Zeitschriftenartikel

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Amon, Alfred1, Autor           
Svanidze, Eteri1, Autor           
Prots, Yurii2, Autor           
Nicklas, Michael3, Autor           
Burkhardt, Ulrich4, Autor           
Ormeci, Alim1, Autor           
Leithe-Jasper, Andreas5, Autor           
Grin, Yuri6, Autor           
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
3Michael Nicklas, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863472              
4Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
5Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              
6Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: The new ternary compound Y4Be33Pt16 was prepared from elements by arc melting, and its crystal structure was determined from single-crystal X-ray diffraction data (space group I (4) over bar 3d, a = 13.4849(3) angstrom). The material is the first representative of a new structure type of complex intermetallic compounds and reveals a cage-like crystal structure. Analysis of chemical bonding by means of the electron localizabilty approach indicates ionic interaction of yttrium with the rest of the crystal structure, characteristic for cage compounds, in particular for clathrates. In contrast to the mostly two-centre bonding in the framework of clathrates, the new compound is characterized by a multi-centre interaction within the framework, caused by the demand of the valence electrons in the system. The non-centrosymmetric material enters the superconducting state at T-C = 0.9 K.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2020-06-252020-06-25
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: ISI: 000549100400022
DOI: 10.1039/d0dt01374a
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Dalton Transactions
  Kurztitel : Dalton Trans.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Cambridge, UK : Royal Society of Chemistry
Seiten: - Band / Heft: 49 (27) Artikelnummer: - Start- / Endseite: 9362 - 9368 Identifikator: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323